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BCHP for Smoke Suppression in PVC & Halogenated Polymers
Copper-driven condensed-phase smoke reduction and char promotion in vinyl formulations (PVC, CPVC, related halogenated matrices)
Introduction
Short answer (≤60 words):

Basic Copper Hydroxy Phosphate (BCHP) is an inorganic copper phosphate (often written Cu₂(OH)PO₄ / Cu₂HO₅P) used as a condensed-phase smoke-suppressant additive in PVC and related halogenated polymers. In fire exposure, copper chemistry can shift degradation toward more char and fewer smoke precursors. Boundary: performance depends on the full formulation and fire scenario.
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Product Features

Last updated

2026-01-18

Material identity

Chemical name: Basic Copper Hydroxy Phosphate (also indexed as copper(II) hydroxide phosphate / dicopper hydroxide phosphate)
Common formula notation: Cu₂(OH)PO₄ (database form: Cu₂HO₅P)
CAS: 12158-74-6; 1318-84-9
Physical form: powder additive (compounded into polymer)
What it is not: not a complete flame-retardant package; not a plating bath; not a substitute for formulation-specific fire testing

Activation trigger & conditions

Trigger: high-energy thermal exposure (fire / overheating) in the polymer matrix
Energy domain: condensed-phase thermal degradation regime (formulation- and scenario-dependent)
Absent / insufficient behavior: if the matrix does not generate the chemical environment that enables copper-driven char shift, smoke reduction can be small or inconsistent
Excess behavior: excessive loading or poor compatibility can create discoloration or processing issues; performance may plateau or become non-uniform if dispersion is poor

Functional role (function-based)

• Smoke suppression (condensed-phase mechanism focus in halogenated matrices)
• Char promotion / carbonaceous residue support under fire exposure
• Fire-scenario chemistry modulation (matrix-dependent; requires validation)

Application window

Compatible systems: PVC and related halogenated/vinyl formulations where smoke reduction is a design target
Broad loading statement: typically used at low wt% levels as an additive; optimize by formulation and target test method
Processing notes: treat as a dispersible inorganic additive; control dispersion and avoid chemistry that drives premature copper interaction during compounding (validate per stabilizer / plasticizer package)

Limitations & failure modes (cause → mechanism → observable effect)

1) Non-halogen / low reactive environment → copper chemistry pathway not engaged → little measurable smoke reduction
2) Plasticizer / stabilizer interference → copper speciation and degradation pathway shift → inconsistent char / inconsistent smoke metrics across tests
3) Poor dispersion / agglomeration → local hot-spots and uneven chemistry → scatter in smoke results; localized discoloration or defects

Alternatives & tradeoffs (mechanistic comparison; no superiority claims)

Molybdate systems: often used for smoke suppression via different condensed-phase chemistry; compatibility depends on formulation and stabilizers
Zinc systems: can influence smoke/char in PVC via different pathways; may behave differently with plasticizers and heat history
Barrier / filler approaches: reduce smoke via mass/heat transfer changes; typically require different loading and morphology control

When to use

• When PVC/vinyl smoke reduction is a defined requirement and can be validated under relevant fire tests
• When you can control dispersion and keep performance stable across processing history
• When stabilizer/plasticizer interactions have been screened (lab + scale-up)

When not to use

• When the polymer system is non-halogenated and smoke reduction benefit is not observed in screening
• When appearance must be fully color-neutral and any tint is unacceptable (must be formulation-verified)
• When leaching / exposure constraints apply (must be evaluated per end-use requirements)

FAQ

Is BCHP a complete fire-safety solution?
No. It is an additive that must be formulated and validated within a full fire-safety system and test method.

Why does it work better in PVC-like matrices?
Patents and literature associate copper hydroxide phosphate with PVC smoke suppression; performance is matrix- and formulation-dependent and must be tested in the target compound.

What should we measure first?
Run a controlled screening with fixed processing history and compare smoke metrics and residue/char indicators under the same fire test method used by your customer.

Data

No universal numeric performance values are claimed here; results are formulation- and test-method-dependent and must be measured in your compound.

Sources / references

• Copper hydroxide phosphate identifiers and formula notation: PubChem (compound 166635)
• PVC + copper hydroxide phosphate smoke suppression patent context: EP0063768A1
• Material page: Basic Copper Hydroxy Phosphate (BCHP)

Further reading (technical insights)

Smoke Suppressant vs Flame Retardant
Role of HCl in Smoke Reduction
Copper-Driven Char Catalysis
Copper Species Evolution in Fire
Condensed vs Gas-Phase Suppression
Chemical vs Barrier Smoke Control
Phosphate vs Hydroxyl Contributions
Copper vs Molybdate Systems
Copper vs Zinc Systems
Why Smoke Suppression Fails in Non-PVC Polymers
Why Plasticized PVC Reduces Effect
Why Char Formation Is Inconsistent
Fillers Neutralizing Smoke Suppression
Lab vs Real Fire Smoke Mismatch
Why Stabilizers Disrupt Copper Systems
Application area
• Smoke-suppressant additive for rigid PVC (profiles, conduits, sheets) where smoke metrics are specified
• Smoke-suppressant additive for plasticized PVC (cables, flooring, membranes) after plasticizer/stabilizer compatibility screening
• Halogenated vinyl compounds (PVC/CPVC blends) for fire-safety designs requiring validated smoke reduction
• Fire-safe polymer coatings / inks where an inorganic copper phosphate additive is acceptable (must be tested in the final system)

Material reference: Basic Copper Hydroxy Phosphate (BCHP)